Pasquill’s Influence: On the Evaporation from Various Liquids into the Atmosphere

C. H. Huang Westinghouse Hanford Company, Richland, Washington

Search for other papers by C. H. Huang in
Current site
Google Scholar
PubMed
Close
Restricted access

Abstract

A theory of evaporation from a plane, free-liquid surface was first introduced by O. G. Sutton. However, in recognizing the shortcomings of Sutton’s theory, F. Pasquill proposed a generalized theory—that is, to modify Sutton’s theory by replacing the air viscosity in the Sutton model with the molecular diffusivity. To verify his theory, Pasquill also carried out a series of experiments. In this study, the author further considers the modification of the Sutton–Pasquill theory by introducing a Schmidt number of −2/3 and provides some theoretical justifications. The results are in very good agreement with the experimental data. In addition, a two-layer evaporation theory that includes an interfacial sublayer is developed.

Corresponding author address: Dr. C. H. Huang, Fluor Daniel Northwest, Inc., P.O. Box 1050, Richland, WA 99352.

Abstract

A theory of evaporation from a plane, free-liquid surface was first introduced by O. G. Sutton. However, in recognizing the shortcomings of Sutton’s theory, F. Pasquill proposed a generalized theory—that is, to modify Sutton’s theory by replacing the air viscosity in the Sutton model with the molecular diffusivity. To verify his theory, Pasquill also carried out a series of experiments. In this study, the author further considers the modification of the Sutton–Pasquill theory by introducing a Schmidt number of −2/3 and provides some theoretical justifications. The results are in very good agreement with the experimental data. In addition, a two-layer evaporation theory that includes an interfacial sublayer is developed.

Corresponding author address: Dr. C. H. Huang, Fluor Daniel Northwest, Inc., P.O. Box 1050, Richland, WA 99352.

Save
  • Bird, R. B., W. E. Stewart, and E. N. Lightfoot, 1966: Transport Phenomena. John Wiley & Sons, 780 pp.

  • Brutsaert, W., 1975: A theory for local evaporation (or heat transfer) from rough and smooth surfaces at ground level. Water Resour. Res.,11, 543–550.

  • Calder, K. L., 1949: Eddy diffusion and evaporation in flow over aerodynamically smooth and rough surface: A treatment based on laboratory laws of turbulent flow with special reference to conditions in the lower atmosphere. Quart. J. Mech. Appl. Math.,2, 153–176.

  • Hanna, S. R., and P. J. Drivas, 1993: Modeling VOC emissions and air concentration from the Exxon Valdez oil spill. J. Air Waste Manage. Assoc.,43, 298–309.

  • Liu, W. T., K. B. Katsaros, and J.A. Businger, 1979: Bulk parameterization of air–sea exchanges of heat and water vapor including the molecular constraints at the interface. J. Atmos. Sci.,36, 1722–1935.

  • MacKay, D., and R. S. Matsugu, 1973: Evaporation rate of hydrocarbon spills on water and land. Can. J. Chem. Eng.,5, 434–439.

  • Pasquill, F., 1943: Evaporation from a plane, free-liquid surface into a turbulent air stream. Proc. Roy. Soc. London, Ser. A,182, 75–94.

  • ——, 1961: The estimation of the dispersion of windborne material. Meteor. Mag.,90, 33–49.

  • Sutton, O. G., 1934: Wind structure and evaporation in a turbulent atmosphere. Proc. Roy. Soc. London, Ser. A,146, 701–722.

All Time Past Year Past 30 Days
Abstract Views 0 0 0
Full Text Views 375 102 9
PDF Downloads 251 73 1