Springtime Photochemical Air Pollution in Osaka: Field Observation

Shinji Wakamatsu National Institute for Environmental Studies, Tsukuba, Ibraki, Japan

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Itsushi Uno National Institute for Environmental Studies, Tsukuba, Ibraki, Japan

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Toshimasa Ohara Institute of Behavioral Sciences, Ichigaya, Shinjuku, Tokyo, Japan

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Abstract

High concentrations of nitrogen dioxide are frequently observed in the Osaka area in the spring. To clarify the mechanism of springtime air pollution formation, a series of three-dimensional field observations was conducted in April 1993 covering Osaka and the surrounding area. During the aircraft observations of 19–21 April 1993, high concentrations of photochemical air pollution were observed over the Osaka area under a stagnant meteorological condition. The maximum observed ozone concentration was more than 150 ppb. The vertical distribution of ozone was uniform up to 2400 m in the daytime. At Mt. Ikoma (600 m), the ozone level was almost constant during the afternoons of 19–20 April 1993, ranging from 80 to 100 ppb, and the presence of aged secondary pollutants was detected in the nighttime. The upper ozone concentration above 3000 m was approximately 60 ppb. The observational results, near the surface and aloft, indicate the importance of photochemically produced ozone and transported background ozone in controlling secondary air pollution covering Osaka and the surrounding area in spring.

Corresponding author address: Dr. Shinji Wakamatsu, Urban Air Quality Research Team, Regional Environment Division, National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba, Ibraki 305-0053 Japan.

Abstract

High concentrations of nitrogen dioxide are frequently observed in the Osaka area in the spring. To clarify the mechanism of springtime air pollution formation, a series of three-dimensional field observations was conducted in April 1993 covering Osaka and the surrounding area. During the aircraft observations of 19–21 April 1993, high concentrations of photochemical air pollution were observed over the Osaka area under a stagnant meteorological condition. The maximum observed ozone concentration was more than 150 ppb. The vertical distribution of ozone was uniform up to 2400 m in the daytime. At Mt. Ikoma (600 m), the ozone level was almost constant during the afternoons of 19–20 April 1993, ranging from 80 to 100 ppb, and the presence of aged secondary pollutants was detected in the nighttime. The upper ozone concentration above 3000 m was approximately 60 ppb. The observational results, near the surface and aloft, indicate the importance of photochemically produced ozone and transported background ozone in controlling secondary air pollution covering Osaka and the surrounding area in spring.

Corresponding author address: Dr. Shinji Wakamatsu, Urban Air Quality Research Team, Regional Environment Division, National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba, Ibraki 305-0053 Japan.

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  • Uno, I., T. Ohara, and S. Wakamatsu, 1996: Analysis of wintertime NO2 pollution in the Tokyo metropolitan area. Atmos. Environ.,30, 703–713.

  • Wakamatsu, S., I. Uno, H. Ueda, K. Uehara, and H. Tateishi, 1989: Observational study of stratospheric ozone intrusions into the lower troposphere. Atmos. Environ.,23, 1815–1826.

  • ——, ——, and M. Suzuki, 1990: A field study of photochemical smog formation under stagnant meteorological condition. Atmos. Environ.,24A, 1037–1050.

  • ——, T. Ohara, and I. Uno, 1996: Recent trend in precursor concentrations and oxidant distribution in the Tokyo and Osaka areas. Atmos. Environ.,30, 715–721.

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