Analysis System for Measurement of CO2 Mixing Ratios in Flask Air Samples

Kirk W. Thoning NOAA/Climate Monitoring and Diagnostics Laboratory, Boulder, Colorado

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Thomas J. Conway NOAA/Climate Monitoring and Diagnostics Laboratory, Boulder, Colorado

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Ni Zhang Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Colorado

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Duane Kitzis Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Colorado

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Abstract

A system for measuring the concentration of CO2 in flask air samples from the NOAA/CMDL worldwide flask sampling network is described. Up to 180 samples per day can he analyzed using a nondispersive infrared CO2 analyzer. All data acquisition and instrument control operations are handled by a Hewlett-Packard Series 300 desktop computer. A noncontaminating diaphragm pump transfers the sample from the flask to the NDIR CO2 analyzer. Tests conducted using flasks filled from tanks of dry air showed either no systematic offsets or a small offset of about 0.1 ppm. The precision of the analysis system is estimated to be better than 0.1 ppm.

Abstract

A system for measuring the concentration of CO2 in flask air samples from the NOAA/CMDL worldwide flask sampling network is described. Up to 180 samples per day can he analyzed using a nondispersive infrared CO2 analyzer. All data acquisition and instrument control operations are handled by a Hewlett-Packard Series 300 desktop computer. A noncontaminating diaphragm pump transfers the sample from the flask to the NDIR CO2 analyzer. Tests conducted using flasks filled from tanks of dry air showed either no systematic offsets or a small offset of about 0.1 ppm. The precision of the analysis system is estimated to be better than 0.1 ppm.

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