A Computer-Controlled Continuous Air Drying and Flask Sampling System

R. E. M. Neubert Centrum voor IsotopenOnderzoek, Groningen, Netherlands

Search for other papers by R. E. M. Neubert in
Current site
Google Scholar
PubMed
Close
,
L. L. Spijkervet Centrum voor IsotopenOnderzoek, Groningen, Netherlands

Search for other papers by L. L. Spijkervet in
Current site
Google Scholar
PubMed
Close
,
J. K. Schut Centrum voor IsotopenOnderzoek, Groningen, Netherlands

Search for other papers by J. K. Schut in
Current site
Google Scholar
PubMed
Close
,
H. A. Been Centrum voor IsotopenOnderzoek, Groningen, Netherlands

Search for other papers by H. A. Been in
Current site
Google Scholar
PubMed
Close
, and
H. A. J. Meijer Centrum voor IsotopenOnderzoek, Groningen, Netherlands

Search for other papers by H. A. J. Meijer in
Current site
Google Scholar
PubMed
Close
Restricted access

We are aware of a technical issue preventing figures and tables from showing in some newly published articles in the full-text HTML view.
While we are resolving the problem, please use the online PDF version of these articles to view figures and tables.

Abstract

A computer-controlled continuous air drying and flask sampling system has been developed and is discussed here. This system is set up for taking air samples automatically at remote places. Twenty glass flasks can be connected one by one or in pairs, and they can be filled at preset times, after preset intervals, or by online remote control. The system is capable of drying air continuously without operator intervention, with a flow rate of up to 4 L min−1, to a dewpoint below −50°C. This enables continuous sampling, always retaining grab air samples of, for example, the last 24 h. This way, it is possible to decide afterward, according to online instrument records, if it is worthwhile to keep a single flask sample or even the whole diurnal cycle for later analysis at the laboratory. Dry sample air can be supplied to other analyzers. Four copies of the instrumentation are active at various places in Europe and have been shown to be able to run without servicing for periods of more than 1 month.

Corresponding author address: Dr. R. E. M. Neubert, Centrum voor IsotopenOnderzoek (CIO), University of Groningen, Nijenborgh 4, NL-9747 AG Groningen, Netherlands. Email: neubert@phys.rug.nl

Abstract

A computer-controlled continuous air drying and flask sampling system has been developed and is discussed here. This system is set up for taking air samples automatically at remote places. Twenty glass flasks can be connected one by one or in pairs, and they can be filled at preset times, after preset intervals, or by online remote control. The system is capable of drying air continuously without operator intervention, with a flow rate of up to 4 L min−1, to a dewpoint below −50°C. This enables continuous sampling, always retaining grab air samples of, for example, the last 24 h. This way, it is possible to decide afterward, according to online instrument records, if it is worthwhile to keep a single flask sample or even the whole diurnal cycle for later analysis at the laboratory. Dry sample air can be supplied to other analyzers. Four copies of the instrumentation are active at various places in Europe and have been shown to be able to run without servicing for periods of more than 1 month.

Corresponding author address: Dr. R. E. M. Neubert, Centrum voor IsotopenOnderzoek (CIO), University of Groningen, Nijenborgh 4, NL-9747 AG Groningen, Netherlands. Email: neubert@phys.rug.nl

Save
  • Conway, T. J., Tans P. P. , Waterman L. S. , Thoning K. W. , Kitzis D. R. , Masarie K. A. , and Zhang N. , 1994: Evidence for interannual variability of the carbon cycle from the National Oceanic and Atmospheric Administration/Climate Monitoring and Diagnostics Laboratory Global Air Sampling Network. J. Geophys. Res, 99 , 2283122855.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • den Besten, J. H., and Neubert R. E. M. , 1998: A Nafion-based gas drying system. CIO-RuG Internal Rep. CIO-IR/15/98, Centre for Isotope Research, University of Groningen, Groningen, Netherlands, 22 pp.

    • Search Google Scholar
    • Export Citation
  • Francey, R. J., Tans P. P. , Allison C. E. , Enting I. G. , White J. W. C. , and Trolier M. , 1995: Changes in oceanic and terrestrial carbon uptake since 1982. Nature, 373 , 326330.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Gemery, P. A., Trolier M. , and White J. W. C. , 1996: Oxygen isotope exchange between carbon dioxide and water following atmospheric sampling using glass flasks. J. Geophys. Res, 101 , 1441514420.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Keeling, C. D., Whorf T. P. , Wahlen M. , and van der Plicht J. , 1995: Interannual extremes in the rate of rise of atmospheric carbon dioxide since 1980. Nature, 375 , 666670.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Keeling, R. F., and Shertz S. R. , 1992: Seasonal and interannual variations in atmospheric oxygen and implications for the global carbon cycle. Nature, 358 , 723727.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Manning, A. C., 2001: Temporal variability of atmospheric oxygen from both continuous measurements and a flask sampling network: Tools for studying the global carbon cycle. Ph.D. thesis, University of California, San Diego, 202 pp.

    • Search Google Scholar
    • Export Citation
  • Meijer, H. A. J., Smid H. M. , Perez E. , and Keizer M. G. , 1996: Isotopic characterisation of anthropogenic CO2 emissions using isotopic and radiocarbon analysis. Phys. Chem. Earth, 21 , 483487.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Severinghaus, J. P., 1995: Studies of the terrestrial O2 and carbon cycles in sand dune gases and in biosphere 2. Ph.D. thesis, Columbia University, 148 pp.

    • Search Google Scholar
    • Export Citation
  • Sturm, P., Leuenberger M. , Sirignano C. , Neubert R. E. M. , Meijer H. A. J. , Langenfelds R. , Brand W. A. , and Tohjiama Y. , 2004: Permeation of atmospheric gases through Viton O-rings used for flask sampling. J. Geophys. Res., in press.

    • Search Google Scholar
    • Export Citation
  • Takahashi, H. A., Konohira E. , Hiyama T. , Minami M. , Nakamura T. , and Yoshida N. , 2002: Diurnal variation of CO2 concentration, Δ14C and δ13C in an urban forest: Estimate of the anthropogenic and biogenic CO2 contributions. Tellus, 54B , 97109.

    • Search Google Scholar
    • Export Citation
  • Tans, P. P., and Coauthors, 2001: Carbon cycle. Climate monitoring and diagnostics laboratory summary, R. C. Schnell, D. B. King, and R. M. Rosson, Eds., Rep. 25, 24–46.

    • Search Google Scholar
    • Export Citation
  • Zondervan, A., and Meijer H. A. J. , 1996: Isotopic characterisation of CO2 sources during regional pollution events using isotopic and radiocarbon analysis. Tellus, 48B , 601612.

    • Search Google Scholar
    • Export Citation
All Time Past Year Past 30 Days
Abstract Views 0 0 0
Full Text Views 484 255 94
PDF Downloads 131 38 3