Development of an Atmospheric Carbon Dioxide Standard Gas Saving System and Its Application to a Measurement at a Site in the West Siberian Forest

T. Watai Global Environmental Forum, Tsukuba, Japan

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T. Machida National Institute for Environmental Studies, Tsukuba, Japan

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K. Shimoyama National Institute for Environmental Studies, Tsukuba, Japan

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O. Krasnov Institute of Atmospheric Optics SB RAS, Tomsk, Russia

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M. Yamamoto Global Environmental Forum, Tsukuba, Japan

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G. Inoue National Institute for Environmental Studies, Tsukuba, Japan

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Abstract

Observations of the atmospheric CO2 concentration from a 90-m tower in Berezorechka, western Siberia, that have taken place since October 2001 were used to characterize CO2 variations over a vast boreal forest area. A new CO2 standard gas saving system was developed that reduced the consumption of standard gases and kept the analysis precision to within 0.3 μmol mol−1. The CO2 day-to-day variation correlated well with atmospheric stability. The average amplitudes of the diurnal variation at 80 m were found to be about 17 and 1.5 μmol mol−1 in July and December 2003, respectively. Extremely high daytime CO2 concentrations of greater than 400 μmol mol−1 were occasionally observed during the winter, which were caused by anticyclonic atmospheric conditions lasting more than several days. Afternoon CO2 values observed at the 80-m height agreed to within 0.4 μmol mol−1 with aircraft CO2 measurements taken in the planetary boundary layer; disagreements were found for anticyclonic conditions in the winter. The afternoon CO2 values reached their maximum in mid-January and their minimum late in July, with the seasonal amplitude of 30.9 μmol mol−1. Compared to observations at background stations, this observation tower recorded a larger seasonal amplitude and earlier occurrence of the seasonal minimum.

* Current affiliation: Marine Works Japan, Ltd., Yokohama, Japan

+ Current affiliation: Institute of Low Temperature Science, Hokkaido University, Sapporo, Japan

# Current affiliation: Research Institute for Humanity and Nature, Kyoto, Japan

Corresponding author address: T. Watai, Marine Works Japan LTD, 4-11-19-304, Kanazawa, Yokohama, 236-0031, Japan. Email: t-watai@nifty.com

Abstract

Observations of the atmospheric CO2 concentration from a 90-m tower in Berezorechka, western Siberia, that have taken place since October 2001 were used to characterize CO2 variations over a vast boreal forest area. A new CO2 standard gas saving system was developed that reduced the consumption of standard gases and kept the analysis precision to within 0.3 μmol mol−1. The CO2 day-to-day variation correlated well with atmospheric stability. The average amplitudes of the diurnal variation at 80 m were found to be about 17 and 1.5 μmol mol−1 in July and December 2003, respectively. Extremely high daytime CO2 concentrations of greater than 400 μmol mol−1 were occasionally observed during the winter, which were caused by anticyclonic atmospheric conditions lasting more than several days. Afternoon CO2 values observed at the 80-m height agreed to within 0.4 μmol mol−1 with aircraft CO2 measurements taken in the planetary boundary layer; disagreements were found for anticyclonic conditions in the winter. The afternoon CO2 values reached their maximum in mid-January and their minimum late in July, with the seasonal amplitude of 30.9 μmol mol−1. Compared to observations at background stations, this observation tower recorded a larger seasonal amplitude and earlier occurrence of the seasonal minimum.

* Current affiliation: Marine Works Japan, Ltd., Yokohama, Japan

+ Current affiliation: Institute of Low Temperature Science, Hokkaido University, Sapporo, Japan

# Current affiliation: Research Institute for Humanity and Nature, Kyoto, Japan

Corresponding author address: T. Watai, Marine Works Japan LTD, 4-11-19-304, Kanazawa, Yokohama, 236-0031, Japan. Email: t-watai@nifty.com

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  • Baker, D. F., and Coauthors, 2006: TransCom 3 inversion intercomparison: Impact of transport model errors on the interannual variability of regional CO2 fluxes, 1988–2003. Global Biogeochem. Cycles, 20 , GB1002. doi:10.1029/2004GB002439.

    • Search Google Scholar
    • Export Citation
  • Bakwin, P. S., Tans P. P. , Zhao C. , Ussler W. , and Quesnell E. , 1995: Measurement of carbon dioxide on a very tall tower. Tellus, 47B , 535549.

    • Search Google Scholar
    • Export Citation
  • Beardsmore, D. J., and Pearman G. I. , 1987: Atmospheric carbon dioxide measurements in the Australian region: Data from surface observatories. Tellus, 39B , 4266.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Belikov, I. B., Brenninkmeijer C. A. M. , Elansky N. F. , and Ral’ko A. A. , 2006: Methane, carbon monoxide, and carbon dioxide concentrations measured in the atmospheric surface layer over continental Russia in the TROICA experiments. Izv. Atmos. Oceanic Phys., 42 , 4659.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Buosquet, P., Peylin P. , Ciais P. , Quéré C. L. , Friedlingstein P. , and Tans P. P. , 2000: Regional changes in carbon dioxide fluxes of land and oceans since 1980. Science, 17 , 13421346.

    • Search Google Scholar
    • Export Citation
  • Ciais, P., Peylin P. , and Bousquet P. , 2000: Regional biospheric carbon fluxes as inferred from atmospheric CO2 measurements. Ecol. Appl., 10 , 15741589.

    • Search Google Scholar
    • Export Citation
  • Conway, T. J., Tans P. P. , Waterman L. S. , Thoning K. W. , Kitzis D. R. , Masarie K. A. , and Zhang N. , 1994: Evidence for interannual variability of the carbon cycle from the National Oceanic and Atmospheric Administration/Climate Monitoring and Diagnostics Laboratory Global Air Sampling Network. J. Geophys. Res., 99 , 2283122855.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Fan, S., Gloor M. , Mahlman J. , Pacala S. , Sarmiento J. , Takahashi T. , and Tans P. , 1998: A large terrestrial carbon sink in North America implied by atmospheric and oceanic carbon dioxide data and models. Science, 282 , 442446.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Haszpra, L., Barcza Z. , Bakwin P. S. , Berger B. W. , Davis K. J. , and Weidinger T. , 2001: Measuring system for the long-term monitoring of biosphere/atmosphere exchange of carbon dioxide. J. Geophys. Res., 106 , (D3). 30573069.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Higuchi, K., Wofsy D. , Chan D. , and Shashkov A. , 2003: Regional source/sink impact on the diurnal, seasonal and inter-annual variations in atmospheric CO2 at a boreal forest site in Canada. Tellus, 55B , 115125.

    • Search Google Scholar
    • Export Citation
  • Iida, T. Y., Ikebe Y. , and Tojo K. , 1991: An electrostatic radon monitor for measurements of environmental radon. Res. Lett. Atmos. Electr., 11 , 5559.

    • Search Google Scholar
    • Export Citation
  • Inoue, H. Y., and Matsueda H. , 2001: Measurement of atmospheric CO2 from a meteorological tower in Tsukuba, Japan. Tellus, 53B , 205219.

    • Search Google Scholar
    • Export Citation
  • Kaminski, T., Heimann M. , and Giering R. , 1999: A coarse grid three-dimensional global inverse model of the atmospheric transport. 2. Inversion of the transport of CO2 in the 1980s. J. Geophys. Res., 104 , 1855518581.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Lloyd, J., and Coauthors, 2002: A trace-gas climatology above Zotino, central Siberia. Tellus, 54B , 749767.

  • Machida, T., and Coauthors, 2001: Temporal and spatial variations of atmospheric CO2 mixing ratio over Siberia. Extended Abstracts, Sixth Int. Carbon Dioxide Conf., Vol. 1, Sendai, Japan, Organizing Committee of Sixth International Carbon Dioxide Conference, 15–20.

    • Search Google Scholar
    • Export Citation
  • Maksyutov, S., Machida T. , Mukai H. , Patra P. , Nakazawa T. , and Inoue G. , and Transcom-3 Modelers, 2003: Effect of recent observations on Asian CO2 flux estimates by transport model inversions. Tellus, 55B , 522529.

    • Search Google Scholar
    • Export Citation
  • Mukai, H., and Coauthors, 2001: Characterization of atmospheric CO2 observed at two-background air monitoring stations (Hateruma and Ochi-ishi) in Japan. Extended Abstracts, Sixth Int. Carbon Dioxide Conf., Vol. 1, Sendai, Japan, Organizing Committee of Sixth International Carbon Dioxide Conference, 108–111.

    • Search Google Scholar
    • Export Citation
  • Nakazawa, T., Murayama S. , Miyashita K. , Aoki S. , and Tanaka M. , 1992: Longitudinally different variations of lower tropospheric carbon dioxide concentrations over the North Pacific Ocean. Tellus, 44B , 161172.

    • Search Google Scholar
    • Export Citation
  • Nakazawa, T., Morimoto S. , Aoki S. , and Tanaka M. , 1993: Time and space variations of the carbon isotopic ratio of tropospheric carbon dioxide over Japan. Tellus, 45B , 258274.

    • Search Google Scholar
    • Export Citation
  • Nakazawa, T., Ishizawa M. , Higuchi K. , and Trivett N. B. A. , 1997a: Two curve fitting methods applied to CO2 flask data. Environmetrics, 8 , 197218.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Nakazawa, T., Sugawara S. , Inoue G. , Machida T. , Makshyutov S. , and Mukai H. , 1997b: Aircraft measurements of the concentration of CO2, CH4, N2O, and CO and the carbon and oxygen isotopic ratios of CO2 in the troposphere over Russia. J. Geophys. Res., 102 , 38433859.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Paris, J-D., and Coauthors, 2008: The YAK-AEROSIB transcontinental aircraft campaigns: New insights on the transport of CO2, CO and O3 across Siberia. Tellus, 60B , 551568.

    • Search Google Scholar
    • Export Citation
  • Peterson, J., Tans P. , and Kitzis D. , 1997: CO2 round-robin reference gas intercomparison. Extended Abstracts, Fifth Int. Carbon Dioxide Conf., Aspendale, VIC, Australia, Commonwealth Science and Industrial Research Organization, 30–33.

    • Search Google Scholar
    • Export Citation
  • Ramonet, M., and Coauthors, 2002: Three years of aircraft-based trace gas measurements over the Fyodorovskoye southern taiga forest, 300 km north-west of Moscow. Tellus, 54B , 713734.

    • Search Google Scholar
    • Export Citation
  • Sidorov, K., Sogachev A. , Langendorfer U. , Lloyd J. , Nepomniachii I. L. , Vygodskaya N. N. , Schmidt M. , and Levin I. , 2002: Seasonal variability of greenhouse gases in the lower troposphere above the eastern European taiga (Syktyvkar, Russia). Tellus, 54B , 735748.

    • Search Google Scholar
    • Export Citation
  • Taguchi, S., 2000: Synthesis inversion of atmospheric CO2 using the NIRE chemical transport model. Inverse Methods in Global Biogeochemical Cycles, Geophys. Monogr., Vol. 114, 239–253.

    • Search Google Scholar
    • Export Citation
  • Tans, P. P., and Conway T. J. , 2005: Monthly atmospheric CO2 mixing ratios from the NOAA CMDL carbon cycle cooperative global air sampling network, 1968-2002. Trends: A Compendium of Data on Global Change, Carbon Dioxide Information Analysis Center. [Available online at http://www.esrl.noaa.gov/gmd/ccgg/iadv/].

    • Search Google Scholar
    • Export Citation
  • Watai, T., Machida T. , Ishizaki N. , and Inoue G. , 2006: A lightweight observation system for atmospheric carbon dioxide concentration using a small unmanned aerial vehicle. J. Atmos. Oceanic Technol., 23 , 700710.

    • Crossref
    • Search Google Scholar
    • Export Citation
  • Winston, G. C., Sundquist E. T. , Stephens B. B. , and Trumbore S. E. , 1997: Winter CO2 fluxes in a boreal forest. J. Geophys. Res., 102 , 2879528804.

  • Zimov, S. A., Davidov S. P. , Voropaev Y. V. , Prosiannikov S. F. , Semiletov I. P. , Chapin M. C. , and Chapin F. S. , 1996: Siberian CO2 efflux in winter as a CO2 source and cause of seasonality in atmospheric CO2. Climatic Change, 33 , 111120.

    • Crossref
    • Search Google Scholar
    • Export Citation
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