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Particles grown from molecular size by ultraviolet irradiation of initially particle-free air were found not to nucleate condensation at slight (∼1%) supersaturations until sufficient time had elapsed. By monitoring the size of the growing particles by use of Nuclepore filters a size/critical supersaturation relationship was obtained and compared with the predictions of nucleation theory. Substantial agreement with the theory resulted.
Particles grown from molecular size by ultraviolet irradiation of initially particle-free air were found not to nucleate condensation at slight (∼1%) supersaturations until sufficient time had elapsed. By monitoring the size of the growing particles by use of Nuclepore filters a size/critical supersaturation relationship was obtained and compared with the predictions of nucleation theory. Substantial agreement with the theory resulted.
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