Article Type:
Research Article

Parameterization of the Optical Properties of Sulfate Aerosols in the Infrared

J. Li Canadian Center For Climate Modeling and Analysis, Meteorological Service of Canada, University of Victoria, Victoria, British Columbia, Canada

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Qilong Min ASRC, The University at Albany, State University of New York, Albany, New York

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Print Publication:
01 Nov 2002
DOI:
https://doi.org/10.1175/1520-0469(2002)059<3130:POTOPO>2.0.CO;2
Page(s):
3130–3140
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Abstract

Parameterizations of absorptance depth for ammonium sulfate [(NH4)2SO4], ammonium bisulfate (NH4HSO4), and sulfuric acid (H2SO4) in the infrared are provided for an eight-band model (covering 340–2500 cm−1) and for 32 individual wavenumbers in order to generate other band schemes. The parameterization is simple in form and in its dependence on relative humidity.

It is found that the aerosol surface infrared forcing can cancel about 12%–24% aerosol surface solar forcing in a clear sky condition. Also the existence of clouds could enhance the ratio of aerosol surface infrared forcing to the aerosol surface solar forcing. In contrast to the solar case, a small mode size distribution does not always produce a larger aerosol surface forcing. Also it is found that the aerosol surface forcing is dependent on the aerosol location. Very simple analysis is presented to help understand the related physics on sulfate aerosol infrared radiative forcing.

Corresponding author address: Dr. Jiangnan Li, Canadian Center For Climate Modeling and Analysis, Meteorological Service of Canada, P. O. Box 1700, University of Victoria, Victoria, BC V8P 2Y2, Canada. Email: Jiangnan.Li@ec.gc.ca

Abstract

Parameterizations of absorptance depth for ammonium sulfate [(NH4)2SO4], ammonium bisulfate (NH4HSO4), and sulfuric acid (H2SO4) in the infrared are provided for an eight-band model (covering 340–2500 cm−1) and for 32 individual wavenumbers in order to generate other band schemes. The parameterization is simple in form and in its dependence on relative humidity.

It is found that the aerosol surface infrared forcing can cancel about 12%–24% aerosol surface solar forcing in a clear sky condition. Also the existence of clouds could enhance the ratio of aerosol surface infrared forcing to the aerosol surface solar forcing. In contrast to the solar case, a small mode size distribution does not always produce a larger aerosol surface forcing. Also it is found that the aerosol surface forcing is dependent on the aerosol location. Very simple analysis is presented to help understand the related physics on sulfate aerosol infrared radiative forcing.

Corresponding author address: Dr. Jiangnan Li, Canadian Center For Climate Modeling and Analysis, Meteorological Service of Canada, P. O. Box 1700, University of Victoria, Victoria, BC V8P 2Y2, Canada. Email: Jiangnan.Li@ec.gc.ca

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