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Jesse O. Bash, Patricia Bresnahan, and David R. Miller

Abstract

This paper presents a review of recent natural surface mercury exchange research in the context of a new modeling framework. The literature indicates that the mercury biogeochemical flux is more dynamic than the current models predict, with interacting multimedia storage and processes. Although several natural mercury emissions models have been created and incorporated into air quality models (AQMs), none are coupled with air quality models on a mass balance basis, and all lack the capacity to explain processes that involve the transport of mercury across atmosphere–surface media concentration gradients. Existing natural mercury emission models treat the surface as both an infinite source and infinite sink for emissions and deposition, respectively, and estimate emissions through the following three pathways: soil, vegetation, and surface waters. The use of these three transport pathways, but with compartmentalized surface storage in a surface–vegetation–atmosphere transport (SVAT) resistance model, is suggested. Surface water fluxes will be modeled using a two-film diffusion model coupled to a surface water photochemical model. This updated framework will allow both the parameterization of the transport of mercury across atmosphere–surface media concentration gradients and the accumulation/depletion of mercury in the surface media. However, several key parameters need further experimental verification before the proposed modeling framework can be implemented in an AQM. These include soil organic mercury interactions, bioavailability, cuticular transport of mercury, atmospheric surface compensation points for different vegetation species, and enhanced soil diffusion resulting from pressure perturbations.

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Steven E. Koch, Wayne Feltz, Frédéric Fabry, Mariusz Pagowski, Bart Geerts, Kristopher M. Bedka, David O. Miller, and James W. Wilson

Abstract

Families of solitary waves (“solitons”) associated with two atmospheric bores on the same day were observed by an unprecedented number of ground-based and airborne profiling systems during the International H2O Project (IHOP). In addition, a very high-resolution numerical weather prediction model initialized with real data was used with success to simulate one of the bores and the evolving soliton. The predicted wave amplitude, phase speed, wavelength, and structure compared well to these extraordinarily detailed observations. The observations suggest that during the active phase (when turbulent mixing was active, which was prior to bore collapse), the bores and waves vigorously mixed dry air from above a nocturnal boundary layer down to the surface. Refractivity computed from near-surface radar observations showed pronounced decreases due to sudden drying during the passage of the bores in this phase, but refractivity increases appeared during the period of bore collapse. During both phases, the bores wafted aerosol-laden moist air up to the middle troposphere and weakened the capping inversion, thus reducing inhibition to deep convection development. The model results indicate that the refractivity decreases near the surface were due to drying caused by downward turbulent mixing of air by the wave circulations. Turbulent kinetic energy was generated immediately behind the bore head, then advected rearward and downward by the solitary waves. During the dissipation stage, the lifting by the bore head produced adiabatic cooling aloft and distributed the very moist air near the surface upward through the bore depth, but without any drying due to the absence of vigorous mixing. Thus, this study shows that the moist thermodynamic effects caused by atmospheric bores and solitons strongly depend upon the life cycle of these phenomena.

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Robert Wood, Matthew Wyant, Christopher S. Bretherton, Jasmine Rémillard, Pavlos Kollias, Jennifer Fletcher, Jayson Stemmler, Simone de Szoeke, Sandra Yuter, Matthew Miller, David Mechem, George Tselioudis, J. Christine Chiu, Julian A. L. Mann, Ewan J. O’Connor, Robin J. Hogan, Xiquan Dong, Mark Miller, Virendra Ghate, Anne Jefferson, Qilong Min, Patrick Minnis, Rabindra Palikonda, Bruce Albrecht, Ed Luke, Cecile Hannay, and Yanluan Lin

Abstract

The Clouds, Aerosol, and Precipitation in the Marine Boundary Layer (CAP-MBL) deployment at Graciosa Island in the Azores generated a 21-month (April 2009–December 2010) comprehensive dataset documenting clouds, aerosols, and precipitation using the Atmospheric Radiation Measurement Program (ARM) Mobile Facility (AMF). The scientific aim of the deployment is to gain improved understanding of the interactions of clouds, aerosols, and precipitation in the marine boundary layer.

Graciosa Island straddles the boundary between the subtropics and midlatitudes in the northeast Atlantic Ocean and consequently experiences a great diversity of meteorological and cloudiness conditions. Low clouds are the dominant cloud type, with stratocumulus and cumulus occurring regularly. Approximately half of all clouds contained precipitation detectable as radar echoes below the cloud base. Radar and satellite observations show that clouds with tops from 1 to 11 km contribute more or less equally to surface-measured precipitation at Graciosa. A wide range of aerosol conditions was sampled during the deployment consistent with the diversity of sources as indicated by back-trajectory analysis. Preliminary findings suggest important two-way interactions between aerosols and clouds at Graciosa, with aerosols affecting light precipitation and cloud radiative properties while being controlled in part by precipitation scavenging.

The data from Graciosa are being compared with short-range forecasts made with a variety of models. A pilot analysis with two climate and two weather forecast models shows that they reproduce the observed time-varying vertical structure of lower-tropospheric cloud fairly well but the cloud-nucleating aerosol concentrations less well. The Graciosa site has been chosen to be a permanent fixed ARM site that became operational in October 2013.

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Philip A. Feiner, William H. Brune, David O. Miller, Li Zhang, Ronald C. Cohen, Paul S. Romer, Allen H. Goldstein, Frank N. Keutsch, Kate M. Skog, Paul O. Wennberg, Tran B. Nguyen, Alex P. Teng, Joost DeGouw, Abigail Koss, Robert J. Wild, Steven S. Brown, Alex Guenther, Eric Edgerton, Karsten Baumann, and Juliane L. Fry

Abstract

The chemical species emitted by forests create complex atmospheric oxidation chemistry and influence global atmospheric oxidation capacity and climate. The Southern Oxidant and Aerosol Study (SOAS) provided an opportunity to test the oxidation chemistry in a forest where isoprene is the dominant biogenic volatile organic compound. Hydroxyl (OH) and hydroperoxyl (HO2) radicals were two of the hundreds of atmospheric chemical species measured, as was OH reactivity (the inverse of the OH lifetime). OH was measured by laser-induced fluorescence (LIF) and by taking the difference in signals without and with an OH scavenger that was added just outside the instrument’s pinhole inlet. To test whether the chemistry at SOAS can be simulated by current model mechanisms, OH and HO2 were evaluated with a box model using two chemical mechanisms: Master Chemical Mechanism, version 3.2 (MCMv3.2), augmented with explicit isoprene chemistry and MCMv3.3.1. Measured and modeled OH peak at about 106 cm−3 and agree well within combined uncertainties. Measured and modeled HO2 peak at about 27 pptv and also agree well within combined uncertainties. Median OH reactivity cycled between about 11 s−1 at dawn and about 26 s−1 during midafternoon. A good test of the oxidation chemistry is the balance between OH production and loss rates using measurements; this balance was observed to within uncertainties. These SOAS results provide strong evidence that the current isoprene mechanisms are consistent with measured OH and HO2 and, thus, capture significant aspects of the atmospheric oxidation chemistry in this isoprene-rich forest.

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Nirnimesh Kumar, James A. Lerczak, Tongtong Xu, Amy F. Waterhouse, Jim Thomson, Eric J. Terrill, Christy Swann, Sutara H. Suanda, Matthew S. Spydell, Pieter B. Smit, Alexandra Simpson, Roland Romeiser, Stephen D. Pierce, Tony de Paolo, André Palóczy, Annika O’Dea, Lisa Nyman, James N. Moum, Melissa Moulton, Andrew M. Moore, Arthur J. Miller, Ryan S. Mieras, Sophia T. Merrifield, Kendall Melville, Jacqueline M. McSweeney, Jamie MacMahan, Jennifer A. MacKinnon, Björn Lund, Emanuele Di Lorenzo, Luc Lenain, Michael Kovatch, Tim T. Janssen, Sean R. Haney, Merrick C. Haller, Kevin Haas, Derek J. Grimes, Hans C. Graber, Matt K. Gough, David A. Fertitta, Falk Feddersen, Christopher A. Edwards, William Crawford, John Colosi, C. Chris Chickadel, Sean Celona, Joseph Calantoni, Edward F. Braithwaite III, Johannes Becherer, John A. Barth, and Seongho Ahn

Abstract

The inner shelf, the transition zone between the surfzone and the midshelf, is a dynamically complex region with the evolution of circulation and stratification driven by multiple physical processes. Cross-shelf exchange through the inner shelf has important implications for coastal water quality, ecological connectivity, and lateral movement of sediment and heat. The Inner-Shelf Dynamics Experiment (ISDE) was an intensive, coordinated, multi-institution field experiment from September–October 2017, conducted from the midshelf, through the inner shelf, and into the surfzone near Point Sal, California. Satellite, airborne, shore- and ship-based remote sensing, in-water moorings and ship-based sampling, and numerical ocean circulation models forced by winds, waves, and tides were used to investigate the dynamics governing the circulation and transport in the inner shelf and the role of coastline variability on regional circulation dynamics. Here, the following physical processes are highlighted: internal wave dynamics from the midshelf to the inner shelf; flow separation and eddy shedding off Point Sal; offshore ejection of surfzone waters from rip currents; and wind-driven subtidal circulation dynamics. The extensive dataset from ISDE allows for unprecedented investigations into the role of physical processes in creating spatial heterogeneity, and nonlinear interactions between various inner-shelf physical processes. Overall, the highly spatially and temporally resolved oceanographic measurements and numerical simulations of ISDE provide a central framework for studies exploring this complex and fascinating region of the ocean.

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