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Sam Miller

Abstract

Boiling is an extreme form of evaporation that occurs when the saturation vapor pressure is equal to the total atmospheric pressure. This paper computes boiling temperature by four different methods and compares the results to data provided in the CRC Handbook of Physics and Chemistry. The first method utilizes a constant value for the latent heat of vaporization (l υ) in the Clausius–Clapeyron equation, and the second method uses a previously published temperature-dependent linear function for l υ. A third method is suggested that begins by deriving a new second-order function for l υ, and then applies this function in an error-reduction loop to determine boiling temperature as a function of pressure. This method for computing boiling temperature shows a mean bias of 0.31°C between mean sea level pressure and 100 hPa and a mean error of less than a tenth of a percent, which is a significant improvement over both of the first two methods. The fourth method uses a fifth-order polynomial, eliminating l υ and making pressure the independent variable, which is used to compute boiling temperature with a mean bias of 0.25°C and a mean error of 0.09% for pressures between mean sea level pressure and 100 hPa.

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William J. Merryfield
,
Johanna Baehr
,
Lauriane Batté
,
Emily J. Becker
,
Amy H. Butler
,
Caio A. S. Coelho
,
Gokhan Danabasoglu
,
Paul A. Dirmeyer
,
Francisco J. Doblas-Reyes
,
Daniela I. V. Domeisen
,
Laura Ferranti
,
Tatiana Ilynia
,
Arun Kumar
,
Wolfgang A. Müller
,
Michel Rixen
,
Andrew W. Robertson
,
Doug M. Smith
,
Yuhei Takaya
,
Matthias Tuma
,
Frederic Vitart
,
Christopher J. White
,
Mariano S. Alvarez
,
Constantin Ardilouze
,
Hannah Attard
,
Cory Baggett
,
Magdalena A. Balmaseda
,
Asmerom F. Beraki
,
Partha S. Bhattacharjee
,
Roberto Bilbao
,
Felipe M. de Andrade
,
Michael J. DeFlorio
,
Leandro B. Díaz
,
Muhammad Azhar Ehsan
,
Georgios Fragkoulidis
,
Sam Grainger
,
Benjamin W. Green
,
Momme C. Hell
,
Johnna M. Infanti
,
Katharina Isensee
,
Takahito Kataoka
,
Ben P. Kirtman
,
Nicholas P. Klingaman
,
June-Yi Lee
,
Kirsten Mayer
,
Roseanna McKay
,
Jennifer V. Mecking
,
Douglas E. Miller
,
Nele Neddermann
,
Ching Ho Justin Ng
,
Albert Ossó
,
Klaus Pankatz
,
Simon Peatman
,
Kathy Pegion
,
Judith Perlwitz
,
G. Cristina Recalde-Coronel
,
Annika Reintges
,
Christoph Renkl
,
Balakrishnan Solaraju-Murali
,
Aaron Spring
,
Cristiana Stan
,
Y. Qiang Sun
,
Carly R. Tozer
,
Nicolas Vigaud
,
Steven Woolnough
, and
Stephen Yeager
Full access
William J. Merryfield
,
Johanna Baehr
,
Lauriane Batté
,
Emily J. Becker
,
Amy H. Butler
,
Caio A. S. Coelho
,
Gokhan Danabasoglu
,
Paul A. Dirmeyer
,
Francisco J. Doblas-Reyes
,
Daniela I. V. Domeisen
,
Laura Ferranti
,
Tatiana Ilynia
,
Arun Kumar
,
Wolfgang A. Müller
,
Michel Rixen
,
Andrew W. Robertson
,
Doug M. Smith
,
Yuhei Takaya
,
Matthias Tuma
,
Frederic Vitart
,
Christopher J. White
,
Mariano S. Alvarez
,
Constantin Ardilouze
,
Hannah Attard
,
Cory Baggett
,
Magdalena A. Balmaseda
,
Asmerom F. Beraki
,
Partha S. Bhattacharjee
,
Roberto Bilbao
,
Felipe M. de Andrade
,
Michael J. DeFlorio
,
Leandro B. Díaz
,
Muhammad Azhar Ehsan
,
Georgios Fragkoulidis
,
Sam Grainger
,
Benjamin W. Green
,
Momme C. Hell
,
Johnna M. Infanti
,
Katharina Isensee
,
Takahito Kataoka
,
Ben P. Kirtman
,
Nicholas P. Klingaman
,
June-Yi Lee
,
Kirsten Mayer
,
Roseanna McKay
,
Jennifer V. Mecking
,
Douglas E. Miller
,
Nele Neddermann
,
Ching Ho Justin Ng
,
Albert Ossó
,
Klaus Pankatz
,
Simon Peatman
,
Kathy Pegion
,
Judith Perlwitz
,
G. Cristina Recalde-Coronel
,
Annika Reintges
,
Christoph Renkl
,
Balakrishnan Solaraju-Murali
,
Aaron Spring
,
Cristiana Stan
,
Y. Qiang Sun
,
Carly R. Tozer
,
Nicolas Vigaud
,
Steven Woolnough
, and
Stephen Yeager

Abstract

Weather and climate variations on subseasonal to decadal time scales can have enormous social, economic, and environmental impacts, making skillful predictions on these time scales a valuable tool for decision-makers. As such, there is a growing interest in the scientific, operational, and applications communities in developing forecasts to improve our foreknowledge of extreme events. On subseasonal to seasonal (S2S) time scales, these include high-impact meteorological events such as tropical cyclones, extratropical storms, floods, droughts, and heat and cold waves. On seasonal to decadal (S2D) time scales, while the focus broadly remains similar (e.g., on precipitation, surface and upper-ocean temperatures, and their effects on the probabilities of high-impact meteorological events), understanding the roles of internal variability and externally forced variability such as anthropogenic warming in forecasts also becomes important. The S2S and S2D communities share common scientific and technical challenges. These include forecast initialization and ensemble generation; initialization shock and drift; understanding the onset of model systematic errors; bias correction, calibration, and forecast quality assessment; model resolution; atmosphere–ocean coupling; sources and expectations for predictability; and linking research, operational forecasting, and end-user needs. In September 2018 a coordinated pair of international conferences, framed by the above challenges, was organized jointly by the World Climate Research Programme (WCRP) and the World Weather Research Programme (WWRP). These conferences surveyed the state of S2S and S2D prediction, ongoing research, and future needs, providing an ideal basis for synthesizing current and emerging developments in these areas that promise to enhance future operational services. This article provides such a synthesis.

Free access