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Yuichiro Takeshita, Brent D. Jones, Kenneth S. Johnson, Francisco P. Chavez, Daniel L. Rudnick, Marguerite Blum, Kyle Conner, Scott Jensen, Jacqueline S. Long, Thom Maughan, Keaton L. Mertz, Jeffrey T. Sherman, and Joseph K. Warren


The California Current System is thought to be particularly vulnerable to ocean acidification, yet pH remains chronically undersampled along this coast, limiting our ability to assess the impacts of ocean acidification. To address this observational gap, we integrated the Deep-Sea-DuraFET, a solid-state pH sensor, onto a Spray underwater glider. Over the course of a year starting in April 2019, we conducted seven missions in central California that spanned 161 glider days and >1600 dives to a maximum depth of 1000 m. The sensor accuracy was estimated to be ± 0.01 based on comparisons to discrete samples taken alongside the glider (n = 105), and the precision was ±0.0016. CO2 partial pressure, dissolved inorganic carbon, and aragonite saturation state could be estimated from the pH data with uncertainty better than ± 2.5%, ± 8 μmol kg−1, and ± 2%, respectively. The sensor was stable to ±0.01 for the first 9 months but exhibited a drift of 0.015 during the last mission. The drift was correctable using a piecewise linear regression based on a reference pH field at 450 m estimated from published global empirical algorithms. These algorithms require accurate O2 as inputs; thus, protocols for a simple predeployment air calibration that achieved accuracy of better than 1% were implemented. The glider observations revealed upwelling of undersaturated waters with respect to aragonite to within 5 m below the surface near Monterey Bay. These observations highlight the importance of persistent observations through autonomous platforms in highly dynamic coastal environments.

Open access
Molly Baringer, Mariana B. Bif, Tim Boyer, Seth M. Bushinsky, Brendan R. Carter, Ivona Cetinić, Don P. Chambers, Lijing Cheng, Sanai Chiba, Minhan Dai, Catia M. Domingues, Shenfu Dong, Andrea J. Fassbender, Richard A. Feely, Eleanor Frajka-Williams, Bryan A. Franz, John Gilson, Gustavo Goni, Benjamin D. Hamlington, Zeng-Zhen Hu, Boyin Huang, Masayoshi Ishii, Svetlana Jevrejeva, William E. Johns, Gregory C. Johnson, Kenneth S. Johnson, John Kennedy, Marion Kersalé, Rachel E. Killick, Peter Landschützer, Matthias Lankhorst, Tong Lee, Eric Leuliette, Feili Li, Eric Lindstrom, Ricardo Locarnini, Susan Lozier, John M. Lyman, John J. Marra, Christopher S. Meinen, Mark A. Merrifield, Gary T. Mitchum, Ben Moat, Didier Monselesan, R. Steven Nerem, Renellys C. Perez, Sarah G. Purkey, Darren Rayner, James Reagan, Nicholas Rome, Alejandra Sanchez-Franks, Claudia Schmid, Joel P. Scott, Uwe Send, David A. Siegel, David A. Smeed, Sabrina Speich, Paul W. Stackhouse Jr., William Sweet, Yuichiro Takeshita, Philip R. Thompson, Joaquin A. Triñanes, Martin Visbeck, Denis L. Volkov, Rik Wanninkhof, Robert A. Weller, Toby K. Westberry, Matthew J. Widlansky, Susan E. Wijffels, Anne C. Wilber, Lisan Yu, Weidong Yu, and Huai-Min Zhang
Free access