1. Introduction
First principles dictate that for any given ambient air mass, the difference between aspirated (well coupled) air temperature that includes ambient water vapor (dry-bulb temperature Ta) and the temperature of the same air mass (wet-bulb temperature Tw) at saturation provides a direct measurement of the amount of water vapor that air mass contains. This estimate can be determined as both relative and absolute quantities (Loescher et al. 2009). In other words, Tw is the temperature that a volume of air would have if cooled adiabatically to saturation at a constant pressure where all the heat energy came from the measured volume of air (Monteith 1965). The importance of this first principle is better realized when the Ta and Tw measured at both a surface level (boundary condition) and at different heights, that is, reference levels, can be used to estimate the evapotranspiration vertically through these two levels, for example, through a leaf or a canopy surface (Slatyer and McIlroy 1961; Alves et al. 2000; Balogun et al. 2002a,b).
Wet-bulb temperature is a basic hydrostatic, physical quantity that can be used to estimate basic physical weather parameters (Stull 2011). Some applied applications of Tw include linking surface and boundary layer flows (Wai and Smith 1998) and interpreting surface scalar fluxes using physical properties (Loescher et al. 2006), while practical applications may be determining the efficiency of industrial coolers (Gan and Riffat 1999), managing hydrological resources (Dunin and Greenwood 1986), and identifying saturated adiabats on thermodynamic isopleths (Stull 2000).
Another commonplace and important application of Tw is in agricultural research and management, and its determination has important implications on agronomic economies. For instance, Tw is used to determine (i) the amount of time and energy required to dry grain to a stable storage moisture content (Schmidt and Waite 1962), (ii) frost protection for fruit crops (e.g., G. Hoogenboom 2012, personal communication), and (iii) minimum temperature forecasts on relatively clear nights (Angström 1920, abstracted in Smith 1920).

Because Eq. (1) [or Eq. (4)] has no direct solution for Tw (or
Noniterative and analytical approaches have been suggested to calculate Tw. Sreekanth et al. (1998) used artificial neural networks that require relative humidity (RH) and the dewpoint temperature (Td) estimates as input variables. Chappell et al. (1974) calculated Tw by estimating the amount of dry air needed to dry a given mass of moist air through an isobaric and adiabatic procedure, and they reported an accuracy of ±1°C across ambient ranges of atmospheric temperature and pressure when wet-bulb depressions were <30°C. Chau (1980) presented empirical equations to find the Tw by dividing the psychrometric chart into seven arbitrary ranges that span Ta values of −32° to 260°C and Td values of −32° to 40°C, but found this technique only to be accurate (and valid) at sea level.
The crux of all of the above-mentioned solutions requires known Td temperatures to derive Tw. Alternatively, some studies have combined estimates of Ta and RH with either a third-order polynomial equation for es(
Additional uncertainties are the result in the choice of which value of the psychrometric constant is used, particularly when (i) a constant value is chosen [e.g., 6.53 × 10−4 °C−1 (Tejeda-Martínez 1994), 6.67 × 10−4 (Schurer 1981), and 5.68 × 10−4 °C−1 to 6.42 × 10−4 °C−1 when Tw ≤ 0° and 0° < Tw < 30°C (Simões-Moreira 1999)] and (ii) theoretical estimations of γ outlined in Eq. (1) are being questioned empirically (Simões-Moreira 1999; Loescher et al. 2009). As such, these studies have empirically shown that γ is independent of Ta and Pa (Simões-Moreira 1999; Loescher et al. 2009), and they have demonstrated its value is strongly dependent on Tw (Simôes-Moreira 1999) and the wet-bulb depression (Loescher et al. 2009).
The objective of this study is to derive a direct solution for calculating the Tw at any desired elevation while maintaining the high levels of accuracy needed for most applications. This will be achieved by first finding a direct solution for calculating
2. Methodology
Mathematical derivations


Coefficients for calculating saturated vapor pressure of pure water as a function of temperature after Buck (1981).










Variation of F(
Citation: Journal of Atmospheric and Oceanic Technology 30, 8; 10.1175/JTECH-D-12-00191.1















Relationship between λ (black line) and ζ (dotted line) as a function of temperature when −17° ≤ Ta ≤ 40°C, λ = 0.0014 exp(0.027Ta) with R2 = 0.9998, and ζ = −[3 × 10−07(Ta)3] − [1 × 10−05 (Ta)2] + [2 × 10−05 (Ta)] + 0.0444 with R2 = 0.9999. Note that Ta in the denominator of the λ function has the exponent 2 [Eq. (9b)], whereas its exponent value in ζ is 1 [Eq. (10)], making the shapes of the two functions quite different. Hence, we choose different regression equations.
Citation: Journal of Atmospheric and Oceanic Technology 30, 8; 10.1175/JTECH-D-12-00191.1
3. Results
Validation
The accuracy of the analytical solution derived here for calculating
The quantity
Citation: Journal of Atmospheric and Oceanic Technology 30, 8; 10.1175/JTECH-D-12-00191.1














Difference between Tw Eq. (1) and
Citation: Journal of Atmospheric and Oceanic Technology 30, 8; 10.1175/JTECH-D-12-00191.1
The variation of
Variation of
Citation: Journal of Atmospheric and Oceanic Technology 30, 8; 10.1175/JTECH-D-12-00191.1
The mean absolute error (MAE) and the root-mean-squared errors (RMSE) for the proposed analytical solution were less than 0.15° and 0.2°C, respectively. When Ta was positive, MAE and RMSE were 0.15° and 0.21°C, respectively, but were 0.07° and 0.08°C, respectively, when Ta was <0°C.
4. Conclusions
The wet-bulb temperature is an important psychrometric parameter with implications in environmental, meteorological, and agricultural basic research and applied applications. Historically, the theoretical equation for the Tw has no direct solution, and to find and accurate estimation typically relied upon a trial and error process that requires significant CPU time. On the contrary, the methodology here described, based on second-order polynomial fit, is computationally fast and accurate. In this study, an easy-to-use and accurate analytical solution for calculating the thermodynamic wet-bulb temperature for elevations up to 4500 m above MSL is presented. The reason for this upper bound is because the uncertainty in the psychrometric constant increases to >30% above 4500 m above MSL (Simões-Moreira 1999). Moreover, since the equation for calculating the atmospheric pressure head was used in both methods, we assumed it would not be a significant source of uncertainty and not change the difference between the theoretical and the analytical solutions of Tw. It was found that the wet-bulb temperature for both positive and negative ranges of the air temperature can be simulated by a second-order equation. The suggested technique seems to converge with the other known approach when −17° ≤ Ta < 0°C, so that the maximum difference in predicting Tw did not exceed |0.17|°C. When Ta ≥ 0°C,
Acknowledgments
The authors wish to thank Prof. R. Stull for his response to our inquiry, and also Dr. Th. Bellinger for suggesting useful references that greatly improved the quality of this work. HWL wishes to thank the National Science Foundation under the Grant EF-102980. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the National Science Foundation. The authors are thankful for the thoughtful comments from three anonymous reviewers.
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